Precipitation isotope ratios (O and H) record the history of water phase transitions and fractionation processes during moisture transport and rainfall formation. Here, we evaluated the isotopic composition of precipitation over the central-southeastern region of Brazil at different timescales. Monthly isotopic compositions were associated with classical effects (rainfall amount, seasonality, and continentality), demonstrating the importance of vapor recirculation processes and different regional atmospheric systems (South American Convergence Zone-SACZ and Cold Fronts-CF). While moisture recycling and regional atmospheric processes may also be observed on a daily timescale, classical effects such as the amount effect were not strongly correlated (δ18O-precipitation rate r ≤ –0.37). Daily variability revealed specific climatic features, such as δ18O depleted values (~ –6‰ to –8‰) during the wet season were associated with strong convective activity and large moisture availability. Daily isotopic analysis revealed the role of different moisture sources and transport effects. Isotope ratios combined with d-excess explain how atmospheric recirculation processes interact with convective activity during rainfall formation processes. Our findings provide a new understanding of rainfall sampling timescales and highlight the importance of water isotopes to decipher key hydrometeorological processes in a complex spatial and temporal context in central-southeastern Brazil. 相似文献
To achieve accurate evaluation of evapotranspiration of reference crops (ET0) in Jiangxi, China, in the absence of systematic climatological data, with reference to the FAO-56 Penman–Monteith (P-M) equation, the Priestley-Taylor (P–T) method, the Makkink method, the Hargreaves-Samani (H–S) method, the Irmak-Allen (I-A) method, the Penman1948 (48PM) method, the Penman-Van Bavel (PVB) method, the Baier-Robertson (B-R) method, the improved Baier-Robertson (M-B-R) method, the Schendel (Sch) method, the Turc method, the Jensen-Haise (J-H) method, and the Brutsaert-Stricker (B-S) method were used to evaluate the daily climatological data collected by 26 weather stations in Jiangxi, China, and 17 weather stations in adjacent provinces. The results were compared with each other and parameter rate determination was conducted. The results indicated that the Turc method exhibited optimized applicability before parameter rate determination and the average root mean square error (RMSE) and the average normalized root mean square error (NRMSE) by this method were 0.39 mm/d and 0.157 mm, respectively. However, parameter rate determination led to negligible improvement in accuracy for this method. The Turc method could be directly applied in Jiangxi (except Nanchang). For special distribution of error after parameter rate determination, all methods exhibited significant errors in Northern Jiangxi. Herein, the 48PM method and the B-S method showed good applicability after parameter rate determination and RMSE and NRMSE of data by these methods ranged in 0.06 ~ 0.34 mm/d and 0.08 ~ 0.27, 8 ~ 27%, respectively, and their d-indices were close to 1. The annual over-estimations in weather stations in Jiangxi were below 30 mm. In the absence of data about relative humidity and wind speed, the P–T method was an appropriate simplified method for Jiangxi. In this case, α was slightly lower than the default value (1.05 ~ 1.18), RMSE was within 0.21 ~ 0.66 mm/d, and NRMSE was within 0.08 ~ 0.308 ~ 30%. Accuracy of RMSE, d-index, and NRMSE of data by the P–T method, the I-A method, and the PVB method was consistent with all stations, while that by the Mak method was slightly lower, which could be attributed to severe over-estimation in July and August. RMSE of the H–S method, the B-R method, the M-B-R method, the J-H method, and the Sch method were above 0.75 mm/d and these methods were not suitable for accurate evaluation of ET0 in Jiangxi, China. The annual ET0 was calculated by various methods (except the 48PM method and the B-S method) exhibited significant variation around 2003. This may be attributed to significant changes in certain meteorological factors over recent years.
Concentrations of suspended solids in lakes can affect the latter’s primary productivity and reflect changes in sediment deposition. Determining the temporal and spatial distribution of suspended solid concentrations has important significance in lake water environmental management; this is particularly urgent for Poyang Lake, the largest freshwater lake in China. In this study, suspended solid concentration inversion models for Poyang Lake were created using a semi-empirical method with regression analysis between continuously measured suspended solid concentration data and multi-band moderate-resolution imaging spectroradiometer images for spring, summer, autumn, and winter from 2009 to 2012. The coefficient of determination (R2) is from 0.6 to 0.9 and the average relative error for the accuracy verification was between 10 and 30%. The seasonal distributions of suspended solid concentrations in Poyang Lake from 2000 to 2013 were then obtained using optimal reversal models. The results showed that the seasonal variation in suspended solid concentrations had a “W” shape in which high spring and autumn and low summer and winter values. The suspended solid concentrations increased annually from 2000 to 2013 and were mainly distributed in the northern and central portions of the lake, with lower values along the shorelines. Further analysis indicated that the large difference in water level between the wet and dry seasons is an important factor in explaining these seasonal variations. Moreover, the suspended solid concentrations were poorly correlated with water temperature and chlorophyll-a concentration but more highly correlated with the deferred chlorophyll-a concentration. 相似文献
The surface morphology of a rock joint is closely related to its mechanical properties. To reasonably characterize a rock surface, two new roughness parameters were proposed in this paper. One is related to the average slope angle of asperities that contribute to the shear strength, and the other reflects the frictional behavior of asperities that is defined as the maximum possible contact area in the shear direction. Taking the standard joint roughness coefficient profiles as example, these two roughness parameters can be applied to describe the directional characteristics of shear strength. Based on their relationships with initial dilation angles, the proposed roughness parameters were incorporated into a peak shear strength criterion. It is shown that the predicted peak shear strength is consistent with experimental data, and there is a power–law relationship. The application range of new roughness parameters was determined, which may facilitate a measurement process. 相似文献
An oil-based drilling fluid additive H-DEA (or humic acid-cocamide diethanolamine) was synthesised using humic acid and cocamide diethanolamine as raw materials. The rheological behaviors of H-DEA showed that the synthesised product has the good properties in both decreasing the filtrate loss and improving rheology property of oil-based drilling fluids compared with other commercially available additives. Under the optimal additive amount of 3%, both API filtrate loss and yield point changed remarkably from 5.40 to 0.41 mL and 9.0 to 25.6 Pa, respectively. Furthermore, differential scanning calorimetry (DSC) showed that H-DEA has good thermal stability in a wide temperature range up to 170 °C. Infrared spectroscopy (IR) and rheological analysis revealed that the possible mechanism of the multifunctional effects may be attributed to the existing of high density of strong polar groups, hydrogen bonds, electrostatic forces, and intermolecular association on H-DEA molecular structure. The results of the study showed that the synthesised H-DEA can be potentially used as a multifunctional oil-based drilling fluid additive in oil-drilling excavation. 相似文献
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